The old ones are the best

An apocryphal story was doing the rounds of the chemistry discussion groups on the internet a while ago. You can substitute your own alma mater and personal weekend hobby for greater comic effect when relating the tale.

Two undergraduate chemists at Newcastle University did very well in their mid-term exams, their practical results were squeaky clean – both were headed for a first. In fact, the two friends were so certain of their chances they spent the weekend before the crucial final fell walking and partying at a hill-top youth hostel.

Either suffering from all the fresh air or one or two more beers than they should have had on the Sunday night they didn’t make it back to Newcastle until early Monday morning. Rather than taking the crucial final they spoke to Professor Bunsen after the exam and explained that their car got a flat tyre on the way back to University and the spare was dud.

flat-tyre

Bunsen was a lenient chap and agreed they could take the exam the following day. The friends were so relieved and studied hard that night. For the exam they were put in separate rooms and given the question booklet. Question One was a simple test of chemical reactions (5 points) and each thought the exam was going to be easy. They were unprepared, however, for what they saw on the next page. It said: “Which tyre? (95 points)”.

In the poo of Eden

We recently visited the Eden Project near St Austell in Cornwall and were impressed not only by the vast “biomes” and their horticultural contents but by the detail into which the designers of some of the exhibits have gone. Particularly intriguing was the Spindigo exhibit that is being undertaken with researchers at the University of Reading. Spindigo as the name might hint at, aims to find a sustainable way to supply the textile industry with the unique blue jeans dye indigo from natural renewable resources rather than synthetic chemicals. Certainly a worthwhile cause.

The Spindigo exhibit went into some detail about how all kinds of natural materials have been used to release the blue colouring from its natural plant sources. The seemingly endless list included dates, grapes, yeast, molasses, figs, papaya, green bananas. Our colleague began to wish he hadn’t visited the Eden Project’s restaurant for a “Cornish pastie” when he got further down the list. Rotten meat as well as urine (they don’t mention whose) have also been used to extract the blue. But, the last entry was the most off-putting – dog poo! On reflection though, perhaps this secret ingredient is part of what makes those shrink-to-fit jeans so trendy. Just don’t tell the marketing department.

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The Real Butterfly Effect

The tropical butterfly Morpho sulkowskyi flashes bright blue as its iridescent wings flutter by. Not only is it astonishingly beautiful, but Japanese chemists believe the secret of what gives these wings their brilliance could lead to a new approach to stay-clean coatings for cars and other surfaces.

Osamu Sato of the Kanagawa Academy of Science and Technology and colleagues have discovered the secret of why the butterfly’s shiny wings never seem to get dirty and intend to put their discovery to good use.

They already knew that butterfly wings have a special surface structure. This consists of an array of highly ordered microscopic scales, which produce colour by scattering and refracting light from the scales. This “structural colouring” is unlike the colourful pigments used elsewhere in the natural world which rely on reflecting light at different wavelengths. Structural colour, however, unlike a baboon’s rear, relies on keeping pristine, otherwise the butterfly would revert to a dull grey.

Sato and his team discovered that there are countless air-filled cavities within the scaly surface of the wing. These, he explains, carry out cleansing duties across the wing’s surface. Any minute droplets of water on the surface ride on a cushion of air and as they roll off they drag with them any clinging dirt particles. This helps maintains the scales’ smooth lustre.

Now, the team have copied the butterfly effect. First, they produced a liquid suspension containing finely divided polystyrene beads just a few micrometres across. They then added powdered silicate whose particles are a few tenths the diameter of the beads. A blast of ultrasound makes the particles disperse evenly throughout the liquid. The researchers then dipped a glass slide into this mixture and slowly withdrew it.

As the plastic beads stick to the slide, they pack together like so many apples on a tray into an arrangement known as hexagonal close packing. The beads act as a template for the silicate particles, which fill the gaps between the beads. “During the lifting process, the polystyrene beads self-assemble into a highly ordered structure,” explains Sato. It is the patterned silicate layer in which the researchers are interested though so they next burn off the polystyrene beads at 450 Celsius. This leaves behind a honeycomb of tiny hollow cells formed from the compacted silicate particles.

Size is important when it comes to hollow air pockets. To mimic the colourful effects of the butterfly wing, the holes have to have a diameter close to the wavelength of visible light so they can scatter incoming light waves, explains Sato. By changing the size of the templating beads, the researchers, can fine tune the diameter. In this way, they have made brilliant blue, green and red layers and could produce all the colours in between.

Their preliminary tests show that these silicate layers, are water repellent because of their air holes. Thus, like the butterfly’s wing any droplets of water are dispersed readily and dirt particles carried away with them. “The sample is not yet very tough, it will peel off if it is scratched,” confesses Sato, “but we are collaborating with Japanese companies to solve this problem.”

The researchers say their new materials might first find use in quantum dot devices, as optical materials for telecommunications, and as scaffolds for tissue engineering. More immediately commercial applications may be possible such as the self-cleaning car. Whatever colour it is to be, such a vehicle with its butterfly-wing coating is sure to cause a flap.

Good anger, bad anger

Anger management is not all about controlling and stifling anger especially if you want to be good to your heart.

It’s not five minutes since researchers revealed that anger, particularly among men could cause heart problems. Now, it seems a different group has observed the opposite effect – expressing anger may protect against heart attack and stroke. So, should we chill out or indulge that road rage? Vote now.